When a lithium battery is subjected to a current draw that exceeds its designed limits, several detrimental effects can occur:Heat Generation Excessive current leads to significant heat generation. . Voltage Drop High current draw results in a substantial voltage drop across the battery’s terminals. . Electrochemical Degradation The rapid movement of ions under high current conditions can accelerate the degradation of the battery’s electrodes. . [pdf]
The number of ions in the electrolyte can be quantified by the state of charge (SOC) of the battery. The higher the number of ions in the battery, the greater will be its SOC. So an increase in battery voltage leads to an increase in SOC and consequently a reduction in energy storage ability.
It is also noticed that, the efficiency of the battery sharply increases when the charging current surpasses the discharge current, it is explained using Peukert’s law which states that, “As the rate of discharge of the battery increases, the battery's available capacity decreases”.
Therefore, nearly all the over-discharged batteries present a linear degradation rate as the over-discharge cycling proceeds, 0.05%/cycle. The impact of current rate on the degradation is revealed by influencing the cycle time, whereby a high current rate usually brings about a shorter cycle time and further accelerates the degradation.
Based on these results, current draw and temperature differences have an influence over the effective battery energy capacity of common AAA batteries. Larger discharge currents consistently led to a lower measurable, starting voltage and faster overall drain. The batteries also showed a difference in the overall total energy output.
On the other side of the temperature spectrum, electrical resistance increases with heat, so warm batteries will inherently have higher internal resistances. These observations point to the possibility that temperature extremes may have apparent effects on the effective energy capacity of batteries.
With the increase of cycle rate, it is shown that the degradation behavior is worsened, with degradation rates of 0.013, 0.021, 0.031 and 0.036%/h corresponding to the 0.5, 1, 2 and 3C conditions, respectively. In other words, a high cycle rate can accelerate battery degradation during the over-discharge cycling.
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