Organic material-based rechargeable batteries have great potential for a new generation of greener and sustainable energy storage solutions [1, 2].They possess a lower environmental footprint and toxicity relative to conventional inorganic metal oxides, are composed of abundant elements (i.e. C, H, O, N, and S) and can be produced through more eco-friendly
Necessary diversification of battery chemistry and related cell design call for investigation of more exotic materials and configurations, such as solid-state potassium batteries. In the core...
This Review describes recent progress in the fundamental understanding of inorganic solid electrolytes, which lie at the heart of the solid-state battery concept, by addressing key issues in...
2 REDOX-ACTIVE INORGANIC MATERIALS FOR REDOX FLOW BATTERIES Wind energy storage Household energy storage Fuel production EV charging Charge station Electrolyte charging Remote energy storage H 2, CXHYOZ Grid balance Commercial
Given the limited availability of transition-metal resources and heavy energy consumption, the production of commercialized metallic charge carrier-based batteries is neither sustainable nor environmentally benign. 150 – 152 In comparison with conventional rechargeable batteries relying on transition-metal-oxide-based materials, the employment of OEMs in
Then the successful commercialization of LIBs featuring inorganic electrode materials in 1991 somewhat lowered the motivation to investigate organic electrode materials. It was not until 2002 that the organic radical compound, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), was proven to possess redox activity in lithium batteries. 24 With the
Different from other reviews on potassium-ion battery electrode materials [3, 10], this review not only introduces the influence of inorganic materials on the performance, but also presents the design strategies of planar structure, hetero-atom doping and lattice frame for all types of electrode materials to improve the electrochemical
Insets are magnified sections that highlight the three main challenges facing solid-state batteries with metal anodes: (1) inhomogeneous metal deposition, (2) formation of blocking interface and...
Organic batteries using redox-active polymers and small organic compounds have become promising candidates for next-generation energy storage devices due to the abundance, environmental benignity, and diverse
The present paper aims at providing a global and critical perspective on inorganic electrode materials for lithium-ion batteries categorized by their reaction mechanism and structural dimensionality. Specific emphasis is put on recent research in the field, which beyond the chemistry and microstructure of the materials themselves also involves
Solid state chemistry and electrochemistry applied to battery materials, covering a wide diversity of technologies with either aqueous or organic electrolytes. These include already commercial (e.g. Ni or Li-ion) or pre-commercial (Na-ion)
This review summarizes recent efforts to apply electrode materials for Li-ion batteries with multi-electron reaction, Li-S batteries, and efficient electrocatalysts for Li-O2 batteries. The methods to enhance the cycling and rate performance have been discussed in detail. Advanced rechargeable Li batteries with multi-electron reaction will
Inorganic all-solid-state sodium batteries (IASSSBs) are emerged as promising candidates to replace commercial lithium-ion batteries in large-scale energy storage systems due to their potential advantages, such as abundant raw materials, robust safety, low price, high-energy density, favorable reliability and stability. Inorganic sodium solid
The present paper aims at providing a global and critical perspective on inorganic electrode materials for lithium-ion batteries categorized by their reaction mechanism and structural dimensionality. Specific emphasis
Different from other reviews on potassium-ion battery electrode materials [3, 10], this review not only introduces the influence of inorganic materials on the performance, but also presents the
Necessary diversification of battery chemistry and related cell design call for investigation of more exotic materials and configurations, such as solid-state potassium batteries. In the core...
Solid state chemistry and electrochemistry applied to battery materials, covering a wide diversity of technologies with either aqueous or organic electrolytes. These include already commercial (e.g. Ni or Li-ion) or pre-commercial (Na-ion) concepts, as well as new emerging chemistries such as those based on Mg or Ca. Emphasis is placed on
This Review describes recent progress in the fundamental understanding of inorganic solid electrolytes, which lie at the heart of the solid-state battery concept, by
Inorganic all-solid-state sodium batteries (IASSSBs) are emerged as promising candidates to replace commercial lithium-ion batteries in large-scale energy storage systems due to their potential advantages, such as abundant raw materials, robust safety, low price, high-energy density, favorable reliability and stability. Inorganic sodium solid electrolytes (ISSEs)
Organic materials can serve as sustainable electrodes in lithium batteries. This Review describes the desirable characteristics of organic electrodes and the corresponding batteries and how we
Herein, we review the current development of inorganic cathode materials targeting for the exploration and development of high-performance potassium ion batteries on introducing (i) inorganic cathode materials including Prussian blue and its analogs, layered metal oxides, and polyanionic inorganic materials, (ii) the crystal structure, storage
This review summarizes recent efforts to apply electrode materials for Li-ion batteries with multi-electron reaction, Li-S batteries, and efficient electrocatalysts for Li-O2 batteries. The methods to enhance the cycling and rate performance
Solid-state electrolytes hold great promise for advancing electrochemical energy storage devices. Advanced batteries based on solid electrolytes, particularly all-solid-state lithium-metal batteries, hold the potential to simultaneously address both high energy density and safety concerns associated with traditional lithium-ion batteries
The combination of inorganic materials (TiS 2 or Mo 6 S 8) with OEMs (PTCDA or HATN) endowed the whole OEMs-based battery with high energy density, and a 30 mAh-level Li/PTCDA-TiS 2 pouch cell displayed a high gravimetric energy of 153 Wh kg –1 in Figure 21B. Besides, Yao''s group reported several aqueous full batteries with quinone anodes and common
With the rapid development of electronic devices and electric vehicles, people have higher requirements for lithium-ion batteries (LIBs). Fast-charging ability has become one of the key indicators for LIBs. However, working under high current density can cause lithium dendrite growth, capacity decay, and thermal runaway. To solve the problem, it is necessary to
Unlike inorganic cathode materials, the electrochemical behaviors of the organic cathode materials depend mainly on active functional groups instead of a crystalline structure. Generally, organic cathode materials with various functional groups can realize charge storage via different charge states derived from redox-active moieties, including n-, p-, or bipolar-type.
Solid-state electrolytes hold great promise for advancing electrochemical energy storage devices. Advanced batteries based on solid electrolytes, particularly all-solid-state lithium-metal batteries, hold the
Insets are magnified sections that highlight the three main challenges facing solid-state batteries with metal anodes: (1) inhomogeneous metal deposition, (2) formation of blocking interface and...
Inorganic all-solid-state sodium batteries (IASSSBs) are emerged as promising candidates to replace commercial lithium-ion batteries in large-scale energy storage systems due to their potential advantages, such as
Fast-ion conductors or solid electrolytes lie at the heart of the solid-state battery concept. Our aim in this Review is to discuss the current fundamental understanding of the material properties of inorganic solid electrolytes that are relevant to their integration in solid-state batteries, as shown in Fig. 1.
The positive electrode materials of potassium ion batteries mainly include Prussian blue analogs, layered metal oxides, polyanionic compounds, and organic materials. The negative electrode materials are generally carbon-based materials, alloys, and metal oxides. The electrolytes basically follow the electrolyte system of lithium-ion batteries.
The performance of cathode materials is a critical factor of the potassium ion battery, which directly affects the battery energy density, cycle life, and safety. Nevertheless, inorganic cathode materials play an important role in the research of potassium ion battery cathode materials.
New materials and configurations are necessary to diversify battery chemistry and cell design. This Review focuses on the chemistry, fundamental properties, and status of materials in inorganic solid-state potassium electrolytes.
The global trend towards decarbonization has led to research on battery materials taking centre stage as one of the key enabling technologies for the electrification of transport and the storage of intermittently produced solar and wind energy.
In recent years, significant progress has been made in the study of the design of inorganic electrode materials. Herein, we review the cathode materials (Prussian blue and its analogues, layered oxides and polyanionic compounds) and the anode materials (antimony-based, selenium-based and bismuth-based compounds).
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